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Do color change gems need to have chromium? (Not color shifters)

Garry H (Cut Nut)

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We have debated and decided (with my store gemmo's) that color shift gems only change about one hue in different light.
Color change on the other hand all seem to have just enough chromium - at least all we have seen lightup pink reddish in very long way UV.
 

JackTrick

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IIRC, vanadium can also cause color change. Naturally, it often accompanies chromium, but I believe vanadium tends to be the dominant source of color change in cc garnets and color change lab sapphire.
 

Garry H (Cut Nut)

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IIRC, vanadium can also cause color change. Naturally, it often accompanies chromium, but I believe vanadium tends to be the dominant source of color change in cc garnets and color change lab sapphire.
Thanks, I guess that makes sense, I think they have some similar chemical properties.
 

Nick_G

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I've seen pics of sapphires from Mogok and the Umba Valley in Tanzania that change from a green to a reddish colour, very similar to alexandrite. This is due to vanadium.
 

Garry H (Cut Nut)

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I've seen pics of sapphires from Mogok and the Umba Valley in Tanzania that change from a green to a reddish colour, very similar to alexandrite. This is due to vanadium.

Sold an Umba last week and that's what prompted the question. It fluoresces pale red in very long wave UV. 405nm
So vanadium also causes fluorescence?
 

Nick_G

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Sold an Umba last week and that's what prompted the question. It fluoresces pale red in very long wave UV. 405nm
So vanadium also causes fluorescence?

I'm not sure if it does, but it could have traces of chromium in there as well. My recent purchase of tsavorites fluoresce a peachy colour, and I wonder if there's a yellow component from the vanadium, adding to the pink/red from chromium?

Rare-earth elements can also produce colour shift effects too, e.g. bastnäsite which is cerium carbonate with fluorine and shifts colour in different lights.
 

Garry H (Cut Nut)

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I'm not sure if it does, but it could have traces of chromium in there as well. My recent purchase of tsavorites fluoresce a peachy colour, and I wonder if there's a yellow component from the vanadium, adding to the pink/red from chromium?

Rare-earth elements can also produce colour shift effects too, e.g. bastnäsite which is cerium carbonate with fluorine and shifts colour in different lights.

My Umba is change not shift Nick
 

JackTrick

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Sold an Umba last week and that's what prompted the question. It fluoresces pale red in very long wave UV. 405nm
So vanadium also causes fluorescence?

To clarify, are you saying that fluorescence is what had you label it as color change? Or it was a color change sapphire that also fluoresced?
 

Garry H (Cut Nut)

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My definition of color shift is around one hue change based on illumination warm cool light source .
Color change is induced by various elements (rare earths etc) and often occurs across the spectrum. e.g. Alexandrite and Umba sapphires go green to pinkish red. skipping orange and yellow!
 
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This is such an interesting conversation. I have nothing intelligent to add, so I'm just enjoying the free seminar.
martini.gif
 

Double E

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I am pretty interested in that colour changing umba sapphire. I guess more price friendly than alex??8)
 

Nosean

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Two gemstones with a reverse alexandrite color change are

Tourmaline from Mozambique - unheated with bluepurple in daylight and green in incandescent light. Copper and Manganese.


Zircon from Mogok (Myanmar) - heated with HREE. Again purple in daylight and green in incandescent light.




The tourmalines are extremely rare - never seen one live.

The RCC Zircon are rare and quite expensive compared the other Zircon varieties.
 
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Nosean

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Sapphires from Madagascar (blueviolet to pink) and Tanzania (alexandrite-like).

 

Garry H (Cut Nut)

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Two gemstones with a reverse alexandrite color change are

Tourmaline from Mozambique - unheated with bluepurple in daylight and green in incandescent light. Copper and Manganese.


Zircon from Mogok (Myanmar) - heated with HREE. Again purple in daylight and green in incandescent light.




The tourmalines are extremely rare - never seen one live.

The RCC Zircon are rare and quite expensive compared the other Zircon varieties.
All these except the ziron would be color shift stones with no hanky panky from trace elements.
The last one - zircon on the right - changes same as alexandrite, greenish in cool and pinkish in warm light. No reversal there. Bit it is a color change.
 

Nosean

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Alexandrite is green in daylight - the RCC Zircon and the tourmaline is green in incandescent light. It is an reverse color change.
 

Garry H (Cut Nut)

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That is a color shift from teal greenish blue to blueish green (no purple there as can be seen in the paint eyedropper)

1666766111471.png

The green stone is closer to blue than it is to green.
So this stone is a color shift, not a color change Nosean.
1666766577211.png
 

Nosean

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Maybe you contact Dr. Palke (GIA) for further informations.
 
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